Hi Brent, there's a rule of thumb with acrylic that you should never load them into a dry brush
If the bristles are damp and the problem still occurs (and it does) then I think that explanation is bogus. Although capillary action may play some part evaporation is always going to be the major factor.
With the diluted paints generally used in the hobby there's a lot of water anyway, even straight from the container Vallejo, Andrea, P3, GW, etc. have a significant water percentage in 'em, otherwise they wouldn't be fluid. Acrylic/vinyl paints dry by evaporation and this is fast. That's most of it; the drier the environment the worse this is, so if you live in an area with low humidity you'll tend to have much more trouble in this are than someone who lives somewhere with high humidity.
The general ways around this are adding a retarder of some kind, reloading the brush regularly (good habit to rinse thoroughly and often, helps brushes stay cleaner too) or painting faster. Or some combination of these.
Brent Fordham said:
So, generally, oil brushes are natural bristle and acrylic are synthetic?
Not really. Lots of brushes are multi-use anyway, regardless of how they're marketed to artists. Some oil painters - painters, working on canvas etc. - use all synthetics instead of hog bristle and some acrylic painters use hog bristle instead of synthetics, sable/Kolinsky rounds tend to be used by all types, and so on. Basically people use what they like a lot of the time, even if it's no 'supposed' to be for their medium.
Brent Fordham said:
One problem that I've had when detail painting with acrylic is that the brush dries out too quickly. I have been using W & N Series 7 (sharpest points I've ever found). Should I be trying to find a synthetic bristle alternative?
There is more than one type of Series 7 brush, you may be using the miniature version. Although of course a 0000 is small in any range the miniature type has much shorter bristles and less paint in the brush head = faster drying. This is one of the main reasons I recommend using the largest brush possible generally.
Einion